Producing Biodiesel by the Transesterification Process

Written by:  • Edited by: Lamar Stonecypher
Updated Nov 17, 2011
• Related Guides: Biodiesel | Vegetable Oil

Biodiesel, a renewable fuel, is produced from vegetable oils and animal fats by a process called transesterification. It breaks down the molecules of vegetable oils into constituent molecules forming biodiesel as the main product and glycerin as the byproduct.

Sources of Biodiesel

Biodiesel is manufactured from the vegetable oils like soya, canola, jatropha, sunflower seed, algae, etc. and animal fats. The chemical name for biodiesel is fatty acid alkyl esters. There are a few methods for production of biodiesel, but the most commonly used method for production of biodiesel is known as transesterification. It is the chemical conversion process of vegetable oil or animal fats to biodiesel.

Filling up at the Propel biodiesel pump

Image courtesy Spencer T. (Flickr) under Creative Commons ShareAlike 2.02

Chemical Components of Vegetable Oil

The main components used for production of biodiesel are vegetable oil or animal fats. Vegetable oils are triglycerides that are composed of three chains of fatty acids all connected together by a glycerin molecule. The triglycerides are not the individual atoms; instead they are esters. The esters in turn are the acids, say like fatty acids, that have been combined with alcohol. The chemical name for glycerin is glycerol, which is a form of alcohol.

Process of Transesterification

Transesterification is a chemical reaction used for the conversion of vegetable oil to biodiesel. In this process vegetable oil is chemically reacted with an alcohol like methanol or ethanol in presence of a catalyst like lye. After the chemical reaction, various components of vegetable oil break down to form new compounds.

The triglycerides are converted into alkyl esters, which is the chemical name of biodiesel. If methanol is used in the chemical reaction, methyl esters are formed, but if ethanol is used, then ethyl esters are formed. Both these compounds are biodiesel fuels with different chemical combinations. In the chemical reaction alcohol replaces glycerin.

Glycerin that has been separated during the transesterification process is released as a byproduct of the chemical reaction. Glycerin will either sink to the bottom of the reaction vessel or come to the surface depending on its phase. It can be easily separated by centrifuges, and this entire process is known as transesterification.

The biodiesel produced by the process of transesterification has much lower viscosity, which makes it capable of replacing petroleum diesel in diesel engines. In earlier years when the process of transesterification was not known, the viscosity of vegetable oil was the major hindrance for its use as a fuel for motor engines. The transesterification process has been able to remove this hindrance.

The byproduct of the transesterification chemical reaction is the glycerin that originally formed the bond between the chains of fatty acids. Glycerin can be used for various purposes. Thus during transesterification process nothing goes to waste. All the products and byproducts are utilized for various purposes.

References

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Comments

Showing all 16 comments
 
Aghilkr Nov 25, 2011 3:29 PM
RE: Producing Biodiesel by the Transesterification Process
can u help me with the energy and material balance in the separation part ?? plzz
hatem lamloum Jun 14, 2011 11:54 AM
transesterification process
hi,
could you help me by documentation about transesterification process, what i need material, machines to product biodiesel from used oil?
thank you very much
ADEBISI Feb 10, 2011 4:17 AM
biodisel
Well sir, i dont really know much about this biodisel, i will like to know more
venu Feb 4, 2011 9:12 AM
mahua oil
hell sir
i request you to send me the full details on transesterification process on mahua oil (biodiesel).
please sir.......
urgent
Heera Jan 13, 2011 11:18 PM
Help
can you pls tell how to do transesterification from chicken feathers for biodiesel production?
karthik Mar 23, 2010 3:42 AM
transesterification to produce bio-diesel
tell me about bio-diesel
sudhakar Mar 7, 2010 1:13 PM
catalyst
hello sir,
i want this T300 catalyst name. this catalyst also used in transesterification process.
sudhakar Mar 7, 2010 12:57 PM
matrial balance for transesterification process
sir,
i want material balance for biodiesel in each section(mixers,
reactors, separators, water-wash ) . it's plant capacity 60 tonns/day
sneha Feb 16, 2010 12:08 PM
neem esterification
hello sir,

i request you to send me the full instructions for making biodiesel from NEEM oil.
sir plz help me it is urgent
Mohan kumar sawrnkar Jan 15, 2010 5:44 AM
Purification og glycerol from ransesterification process
Purification og glycerol from ransesterification process,what need for this process.
Samanth vijayraj Jan 10, 2010 11:28 PM
neem esterification
hello sir,
i request you to send me the full instructions for making biodiesel from NEEM oil.

kashif Dec 24, 2009 5:11 AM
how to make the biodiesel from jatropha oil
sir i request you to send me the full instructions for making biodiesel from jatropha oil. sir i have no any information to this topic so please sir send me full instructions.
joan Dec 16, 2009 8:34 PM
urgent
sir i need the chemical reactions in conversion of coco oil to coco methyl ester. can you help me now?thank you very much!godbless!
xyala khay pastor Oct 1, 2009 8:16 AM
can we also use yellow oleander seeds an a source of biodiesel?
what are theie similarity and differences?????
please,,help me
Haresh Khemani Aug 27, 2009 10:13 AM
Help
Actually I'm yet to cover the article on this topic. In the meantime you can search other sources on Internet.

Thanks,

Haresh
abbas Aug 26, 2009 5:19 AM
help me
Hello Mr Khemani
I need the chemical reactions in transesteriication( conversion algae oil to the biodisel).
can you help me fast?
thanks a lot.
 
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