What is Non-Chlorine Bleach?

Written by:  • Edited by: Niki Fears
Updated Jan 27, 2011
• Related Guides: EPA

Non-chlorine bleach is easier on the environment than standard chlorine bleach. But what exactly is non-chlorine bleach? Does it perform as well as chlorine bleach to whiten clothes and disinfect? Is non-chlorine bleach a safe alternative to chlorine bleach?

Steer Clear of Chlorine Bleach

Bleach
click to enlarge
When you buy standard chlorine bleach at the store, you are buying a 5.25% solution of sodium hypochlorite solution in water. Chlorine is a powerful whitener and disinfectant, but can cause negative health effects in people, plants, and animals. Accidental ingestion of chlorine bleach can cause corrosion of the esophagus and gastrointestinal tract. Inhalation of chlorine gas emitted from household bleach can cause nose and throat irritation.

Chlorine bleach is effective at killing bacteria, viruses, molds, and fungi. When chlorine bleach is released into the environment beneficial organisms can be killed before the chlorine gas evaporates into the air. Using non-chlorine bleach as an alternative ensures the safety of your family and your local water system.

Understanding the Power of Oxidation

To understand how non-chlorine bleach works, you need to know a little chemistry. Colors are visible when a molecule absorbs certain wavelengths of visible light and reflects others. The region of a molecule where this occurs is called a chromophore. When elemental oxygen is present the oxygen reacts with the chromophore and destroys it's structure, thereby eliminating the color.

Different bleaching products act as oxidizing agents, standard chlorine bleach being only one of them. Several other chemical compounds can also whiten clothes through oxidation, including hydrogen peroxide and other common non-chlorine bleach ingredients such as sodium percarbonate and sodium perborate.

Non-chlorine bleaches are effective on stains and spills without destroying the color of the fabric. Their oxidizing powers are not as strong as chlorine bleach. This is why non-chlorine bleaches are "color safe". Non-chlorine whiteners are safer to use around the house and gentler on the environment, too.

Do Non-Chlorine Bleaches Disinfect?

The oxidation process that helps eliminate stains and whiten clothes also acts to destroy cell membranes of small organisms like bacteria and fungi. As mentioned above, non-chlorine bleaches are not as powerful of oxidizing agents as is chlorine bleach. Chlorine bleach, therefore, is more effective at disinfecting than non-chlorine bleaches.

Hydrogen peroxide is a non-chlorine bleach that can kill certain types of microbes through oxidation. Hydrogen peroxide can be used to sanitize countertops and other household surfaces. According to the EPA's online hydrogen peroxide fact sheet, "hydrogen peroxide breaks down rapidly in the environment to oxygen and water, and is not expected to cause adverse effects to humans or the environment when users follow label directions."

To use hydrogen peroxide to kill germs in your home, purchase a bottle of 3% hydrogen peroxide at a grocery or drug store. The solution can be used in many ways: as a kitchen or bathroom counter spray, a sanitizer for cutting boards and dishes, or a disinfecting soak for toothbrushes and sponges.

Shopping for Non-Chlorine Bleach

Many non-chlorine bleaches are available in the laundry section of your local store, offered in powder or liquid forms. Clorox 2 is a

7th Generation Non Chlorine Bleach
click to enlarge
non-chlorine bleach containing hydrogen peroxide as an active ingredient. Other eco-friendly brands include Seventh Generation, BioKleen, and Ecover. Oxyclean and other oxygen-based whiteners are non-chlorine bleaches as well.

Picture Credit

Bleach: http://www.flickr.com/photos/vox_efx/3591789044/

7th Generation Non-Chlorine Bleach: http://www.seventhgeneration.com/Chlorine-Free-Bleach


Comments

Showing all 13 comments
 
Deepinder Jeet Jan 14, 2011 5:17 AM
Chlorine bleach
What is %age of hypochlorite in water?
Karen Dec 5, 2010 11:06 PM
Re.: What is Non-Chlorine Bleach?
Carl, non-chlorine bleach is not merely a weaker solution it is a completely different compound than chlorine bleach.

Chlorine bleach is a naturally occurring element in nature. From wikipedia: In its elemental form (Cl2 or "dichlorine") under standard conditions, chlorine is a powerful oxidant and is used in bleaching and disinfectants, as well as an essential reagent in the chemical industry.
http://en.wikipedia.org/wiki/Chlorine

Many non-chlorine bleaches state hydrogen peroxide and water are the ingredients. A Wikipedia search for hydrogen peroxide finds this description: Hydrogen peroxide (H2O2) is an oxidizer commonly used as a bleach. It is a clear liquid, slightly more viscous than water, that appears colorless in dilute solution. It is used as a disinfectant, antiseptic, oxidizer, and in rocketry as a propellant.[2] The oxidizing capacity of hydrogen peroxide is so strong that it is considered a highly reactive oxygen species.
http://en.wikipedia.org/wiki/Hydrogen_peroxide

Beth, check your local Target or Wal-Mart or whatever store is in your area. I just found chlorine bleach and non-chlorine bleach (hydrogen peroxide & water) for the same price, same size too. Both for $1.47 each.
Beth May 3, 2010 3:48 PM
Can I make my own solution
If the non-chlorine solution is just water, hydrogen peroxide and citric acid, does anyone know what the recipe is? I'd be interested in making my own-it's so expensive to buy it. Thanks
John Apr 5, 2010 2:32 PM
Which type of N/C bleach
Vera Wang's "Simply Vera" WHITE towels contain
30% viscose from bamboo fibers plus 70% cotton.
I would like to know WHICH of the various "non-
chlorine" products AND how much...
would it take to remove blood, coffee and other stains?
Note:
It took approx 5 days of soaking with Oxyclean
to remove body oil stains from an expensive cotton sheet.
I could probably have accomplished the same thing during one hot water cycle with Tide & Clorox.
Anonymous Mar 7, 2010 11:57 PM
bleach
how does it affect us and how deadly is it to us
Thumper Feb 23, 2010 1:36 PM
non-chlorine bleach
Carl - non-chlorine means "no chlorine" it is made up of water, hydrogen peroxide and citric acid. it is a completely different thing with the same outcome.
Art Sand Feb 17, 2010 1:35 AM
Non Chlorine bleach
THe bleach manufacturers will love it! You'll nedd twice as much non-chlorine bleach to get the job done, so prepare to spend, spend, spend!
Lindsay Evans Jan 12, 2010 1:13 PM
RE: What is Non-Chlorine Bleach?
Jenny-
I do recommend non-chlorine bleach as a very good way to remove stains and kill germs in the laundry. Several drops of tea tree oil have also been shown to kill germs in the laundry. Both are good non-toxic solutions.
Carl-
I'm sorry that you are still confused as to how non-chlorine bleaches work. As you know, a drop of chlorine bleach on a garment will remove the chemical dye. A drop of non-chlorine bleach will not. This illustrates the fact that chlorine bleach is a chemically stronger oxidizer than non-chlorine bleaches. I am not a chemical engineer, either, but I do understand that different chemicals react differently under the same circumstances. I hope this helps! = )
Carl Jan 12, 2010 12:27 PM
Non-Chlorine Bleach
You did respond to my question earlier. I am a User, not a chemical engineer. I remain confused. So, no where has anyone explained so I can understand "HOW NON-CHLORINE CAN EFFECTIVELY REMOVED STAINS AND SPILLS W/O REMOVING THE COLOR FROM THE BASE FABRIC. So far, and if someone asks me to describe the difference between chlorine and non-chlorine beach, it will be: non-chlorine , simply stated, is a weaker solution of chlorine bleach. And use non-chlorine with caution, because it may help remove the stains/spills but it may also discolor the basic fabric.
Jenny Jan 12, 2010 12:07 AM
Non-Toxic Disinfectant
I am trying to find the best safest, non-toxic way to disinfect laundry. Is non-chlorine bleach it?
Lindsay Evans Jan 1, 2010 7:41 PM
Chlorine-Free Bleach
Non-chlorine bleaches do not contain chlorine. Chemically, non-chlorine bleaches are completely different products, but act similarly to chlorine bleach (through oxidation) to remove stains and disinfect.
Carl Jan 1, 2010 11:46 AM
Question
Are you telling me non-chlorine bleach is no more than a weaker solution of standard/regular bleach with chlorine?
Lindsey Oct 25, 2009 1:56 PM
RE: What is Non-Chlorine Bleach?
Thanks so much for posting this. I've been wondering about nonchlorine bleach ever since I started using Seventh Generation products a couple years ago.
 
blog comments powered by Disqus
Email to a friend