Click Start, type wf.msc into the Search box and hit Enter and you'll be presented with a screen that you have probably never seen before: Windows Firewall with Advanced Security. Click Action > Properties and you'll be brought to a screen from which you can enable outbound filtering. Easy, huh?
But wait! You probably don't want to enable outbound filtering just yet. Although Windows Firewall provides an abundance of options (see Microsoft's Windows Firewall with Advanced Security Getting Started Guide for more information), the process of configuring it is certainly not for the technically challenged. While most third-party firewalls will alert you each time an outgoing connection attempt is blocked and give you an option to either unblock or to keep on blocking, Windows Firewall does not. Instead, you need to create your own rules from scratch - and that's a task which will be well beyond the capabilities of many users.
There is, however, a solution. Sphinx Software's Vista Firewall Control is available in Free and Plus versions and adds functionality, including notifications of outbound connection attempts, that makes it much easier to control Windows Firewall. In fact, with Vista Firewall Control installed, Windows Firewall will behave in much the same way as a third-party firewall such as ZoneAlarm.
Should you wish to enable outbound filtering in Windows Firewall while still keeping things relatively easy, Vista Firewall Control may well be your best option.