The risks do not end with the launch of the rescue shuttle. The orbital rendezvous and transfer of astronauts present new and untested procedures for NASA. Here is a link that details the docking and astronaut transfer to Endeavour. Atlantis, depending on its condition may or may not be remotely piloted to land, most likely at Edwards Air Force Base. If it cannot land then it will probably be deorbited over the Pacific Ocean to minimize the risk to people on the ground.
I look forward to this mission and hope for a flawless, successful flight that brings Atlantis and her crew safely home and breathes new life into Hubble so we can be even more amazed with its images of the universe. Godspeed, Atlantis!
(For the latest information about the successful final Hubble repair mission, read The Fifth and Final Hubble Repair Mission.)