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The most popular business social network is
LinkedIn. If you are just getting started in social networking, this would be the place to start. LinkedIn allows you to network with people you know, be introduced to others through the people you know, and discuss commonalities in their groups. LinkedIn can be a great resource for finding work - you never know who may recruit you through the website, and there is a job search function where you can post as well as find jobs.
A great social network for entrepreneurs and small businesses is Startup Nation. Startup Nation features a community allowing you to network with other startups and entrepreneurs. It also allows you to place advertisements for your business in their classifieds section.
If you're looking for a way to meet people that can help your business to grow, PartnerUp may be just the right network for you. This website allows you to search and post opportunities, connect with others, and get helpful answers to your business concerns.
Biznik is another social networking website that may be helpful to the entrepreneur. This website features freelancers, small businesses, and entrepreneurs grouped by metropolitan area. You can view the members by the areas they specialize in. After creating a brief profile, read helpful articles, join groups, and track events. You can even post articles to help fellow members.
Twitter and Facebook can both be useful to the entrepreneur, but you have to be careful here. Many people use these two sites for fun, meaning that they don't want to be learning about small businesses on Twitter or Facebook. Make sure that anyone you connect with on the sites is open to the connection and avoid mass add applications.
Finally, don't overlook the blog as an efficient way to network online. By creating posts that generate a discussion response, you can build a following.