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To be a good photographer's assistant, you must be dependable, hardworking, friendly, willing to learn, and have some experience or a basic understanding of whatever subject the photographer is shooting. Most likely you will be in charge of helping to position the model, move lights around, and help organize a photo shoot (scheduling and booking). You will be the photographer's right hand man (or woman).
Being a paid or voluntary assistant does not have to be limited to a subordinate position. If you are good friends with a photographer and you like to shoot the same subjects, chances are you already help each other out and take turns playing the role of an assistant.
Photo by .dr4gon