While vinegar and lemon juice certainly are not harmful to humans, the effects of this acidic pH level on forests, lakes and rivers is great.
When acid rain falls, it is absorbed by the soil and collected by lakes and rivers. The change in the pH of soil can alter the growth of plants and even render some plants unable to grow. When plants die, animals have less to eat and will either move on to another location or simply cease to exist.
In lakes and rivers, the collection of a lower pH and more acidic waters will kill fish and leave the waters inhabitable by water breathing species. Lakes and rivers most affected by acid rain will appear crystal clear but will house less fish populations than waters of more alkaline levels.
The fish eggs or roe are the most effected by acid rain. Fish eggs tend to hatch less often or not at all when gestating in acid waters.