Production of Biodiesel: Transesterification Process

Article by Haresh Khemani (26,714 pts )
Edited & published by Haresh Khemani (26,714 pts ) on Sep 9, 2008

Biodiesel, a renewable fuel, is produced from vegetable oils and animal fats by a process called Transesterification Process. It breaks down the molecules of vegetable oils into constituents molecules forming biodiesel as the main product, and glycerin as the byproduct.

Sources of Biodiesel

Biodiesel is manufactured from the vegetable oils like soya, canola, jatropha, sunflower seed, algae etc. and animal fats. The chemical name for biodiesel is fatty acid alkyl esters. There are a few methods for production of biodiesel, but the most commonly used method for production of biodiesel is called as transesterification. It is the chemical conversion process of vegetable oil or animal fats to biodiesel.

Chemical Components of Vegetable Oil

The main components used for production of biodiesel are vegetable oil or animal fats. Vegetable oils are the triglycerides that comprise of three chains of fatty acids all connected together by a glycerin molecule. The triglycerides are not the individual atoms, they are rather esters. The esters in turn are the acids, say like fatty acids, which have been combined with alcohol. The chemical name for glycerin is glycerol, which is a form of alcohol.

Process of Transesterification

Transesterification is a chemical reaction for conversion of vegetable oil to biodiesel. In this process vegetable oil is chemically reacted with alcohol like methanol or ethanol in presence of catalyst like lye. After the chemical reaction various components of vegetable oil break down to form new compounds.

The triglycerides are converted into alkyl esters, which is the chemical name of biodiesel. If methanol is used in the chemical reaction, methyl esters are formed, while if ethanol is used then ethyl esters are formed. Both these compounds are biodiesel fuels with different chemical combination. In the chemical reaction alcohol replaces glycerin.

Glycerin that has been separated during transesterification process is released as the byproduct of the chemical reaction. Glycerin will either sink to the bottom of reaction vessel or come to the surface depending on its phase. It can be easily separated by the centrifuges. This whole process is called as transesterification.

The biodiesel produced by process of transesterification has much lesser viscosity, which makes it capable to replace petroleum diesel in the diesel engines. In the earlier years when process of transesterification was not known the viscosity of vegetable oil was the major hindrance for its use as the fuel for engine. Transesterification process has been able to remove this hindrance.

The byproduct of the transesterification chemical reaction is glycerin that originally formed bond between the chains of fatty acids. Glycerin can be used for various purposes. Thus during transesterification process nothing goes wasted, all the products and byproducts are utilized for various purposes.

11 Comments

Showing page 1 of 2 (11 Comments)
Mar 23, 2010 3:42 AM
karthik
transesterification to produce bio-diesel
tell me about bio-diesel
Mar 7, 2010 1:13 PM
sudhakar
catalyst
hello sir,
i want this T300 catalyst name. this catalyst also used in transesterification process.
Mar 7, 2010 12:57 PM
sudhakar
matrial balance for transesterification process
sir,
i want material balance for biodiesel in each section(mixers,
reactors, separators, water-wash ) . it's plant capacity 60 tonns/day
Feb 16, 2010 12:08 PM
sneha
neem esterification
hello sir,

i request you to send me the full instructions for making biodiesel from NEEM oil.
sir plz help me it is urgent
Jan 15, 2010 5:44 AM
Mohan kumar sawrnkar
Purification og glycerol from ransesterification process
Purification og glycerol from ransesterification process,what need for this process.
Jan 10, 2010 11:28 PM
Samanth vijayraj
neem esterification
hello sir,
i request you to send me the full instructions for making biodiesel from NEEM oil.

Dec 24, 2009 5:11 AM
kashif
how to make the biodiesel from jatropha oil
sir i request you to send me the full instructions for making biodiesel from jatropha oil. sir i have no any information to this topic so please sir send me full instructions.
Dec 16, 2009 8:34 PM
joan
urgent
sir i need the chemical reactions in conversion of coco oil to coco methyl ester. can you help me now?thank you very much!godbless!
Oct 1, 2009 8:16 AM
xyala khay pastor
can we also use yellow oleander seeds an a source of biodiesel?
what are theie similarity and differences?????
please,,help me
Aug 27, 2009 10:13 AM
Help
Actually I'm yet to cover the article on this topic. In the meantime you can search other sources on Internet.

Thanks,

Haresh
Showing page 1 of 2 (11 Comments)