What happens when the water is at a higher pressure, say, at 100 bar? Then the boiling takes place at 311 deg C and the latent heat of vaporisation is 1318 kJ/kg.
If the water pressure is 200 bar then the boiling takes place at 366 deg C and the latent heat of vaporisation is 584 kJ/kg.
As the pressure increases the boiling temperature increases and the latent heat of vaporisation decreases.
A further increase in pressure and temperature leads us to a point at which the latent heat of vaporisation is zero, or there is no boiling. Water directly becomes steam. This is the Critical Pressure and the Critical Temperature. For steam this occurs at 374 deg C and 220.6 bar.