Before you are in a position to understand what lies behind the tubular structure which emits white milky light, there are certain basic concepts of physics which you certainly need to know. Otherwise you may not be able to fully appreciate what I am saying. Of course we are not going to have a deep physics tutorial here but only a broad overview.
I am sure you have heard that light is a form of energy and as per quantum physics it can be broken down into finite chunks known as photons and it travels in this form. So where do these photons originate from? Well they are released when electrons jump from a higher energy level to a lower energy level. You can read about energy levels and bands in other articles in this channel.
So if there is a way in which electrons can be made to traverse across these energy levels as required, they would continuously keeping jumping up and down and keep releasing photons. This is exactly what happens not only in fluorescent lamps but even the ordinary light bulbs. Only the difference lies in the method of making these electrons jump across the energy barriers.