The first language is learned in childhood in what is known as a 'complete immersion' environment. The child is exposed to the language at all times from everyone he or she comes in contact with. The first language is picked up with a natural ease that cannot be replicated when acquiring a second language, unless the second language is learned simultaneously with the first as happens with many bilingual or trilingual people. Let us look at some of the reasons for this -
Firstly, as already mentioned, the input quality of L1 learning is far greater than L2 learning, no matter if you use direct immersion method for the latter. The child is using L1 for everything all the time. The adult, in contrast, may be using L2 only for specific periods in a day. That aside, there is the distinct difference between imbibing from one's parents and learning from a teacher.
The second thing is motivation. In the case of L1, although perhaps not consciously, the motivating factor is the child's desire to communicate with the people around him or her and fit in. The adult learner is not motivated to the same degree, although factors like wanting to fit in with a new culture or wanting to make a beneficial career change can act as an incentive. Without this kind of motivation, where the acquisition of L2 is relevant to your life, second language learning will be an uphill task.
Thirdly, there is a great deal of difference in how children learn and how an adult learns. In fact, some people think it is rather unreasonable to compare the learning methodologies between the two. The child approaches language learning with a clean slate, so to speak, the adult comes equipped with a whole baggage of prior knowledge and experience. Children have it easier as they have a muscular plasticity that adults don't, which means they are able to master tricky pronunciations and memorize new information much faster. Adults also tend to over-analyze everything based on what they already know, and this can both help and hinder the second language acquisition process.