PGP Desktop Email automatically encrypts, signs, decrypts, and verifies emails sent and received. This achieved through PGP’s email proxy functionality, services, default configurations known as policies and the use of public/private keypairs. It works a treat!
PGP Desktop Email, sometimes referred to as PGP Secure Messaging because it also protects some instant messaging apllications, is explained in detail in my article ‘How to encrypt emails with PGP Desktop Email’ which you can find by following this link along keypairs put in a nutshell.